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Hollow microsphere structure cobalt hydroxide (h-Co(OH)2) was synthesized via an optimized solvothermal-hydrothermal process and applied to activate peroxymonosulfate (PMS) for degradation of a typical pharmaceutically active compound, ibuprofen (IBP). The material characterizations confirmed the presence of the microscale hollow spheres with thin nanosheets shell in h-Co(OH)2, and the crystalline phase was assigned to α-Co(OH)2. h-Co(OH)2 could efficiently activate PMS for radicals production, and 98.6% of IBP was degraded at 10 min. The activation of PMS by h-Co(OH)2 was a pH-independent process, and pH 7 was the optimum condition for the activation-degradation system. Scavenger quenching test indicated that the sulfate radical (SO4? ?) was the primary reactive oxygen species for IBP degradation, which contributed to 75.7%. Fukui index (f ?) based on density functional theory (DFT) calculation predicted the active sites of IBP molecule for SO4? ? attack, and then IBP degradation pathway was proposed by means of intermediates identification and theoretical calculation. The developed hollow Co(OH)2 used to efficiently activate PMS is promising and innovative alternative for organic contaminants removal from water and wastewater. 相似文献
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Zong Chang Feng Liu Liang Wang Mengying Deng Chunhua Zhou Qinchao Sun Jun Chu 《中国化学快报》2019,30(10):1856-1882
Taking the advantage of reduced scattering and low autofluorescence background, the NIR fluorescence probes, such as fluorescence proteins, organic molecules and nanoparticles, not only hold the promise of in vivo imaging of biological processes in physiology and pathology with high signal-to-noise ratio, but also for clinical diagnosis. In this review, we provide an overview of the recent progress on NIR probes, focusing on fundamental mechanisms of NIR dyes and nanoparticles, and protein engineering strategies for NIR proteins. 相似文献
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Xiaoding Lou 《中国化学快报》2019,30(9):1557-1564
The complexity of biological samples determines that the detection of a single biomolecule is unable to satisfy actual needs. Moreover, the “false positives” results caused by a single biomolecule detections easily leads to erroneous clinical diagnosis and treatment. Thus, it is important for the homogenous quantification of multiple biomolecules in not only basic research but also practical application. As a consequent, a large number of literatures have been exploited to monitor multiple biomolecules in homogenous solution, enabling facilitating the development of the disease diagnosis, treatment as well as drug discovery. One-dimensional nanomaterials and two-dimensional nanomaterials have special physical and chemical properties, such as good electrochemical properties, stable structure, large specific surface area, and biocompatibility, which are widely used in electrochemical and fluorescent detection of biomolecules. This tutorial review highlights the recent development for the detection of multiple biomolecules by using nanomaterials including one-dimensional materials (1DMs) as well as two-dimensional materials (2DMs). 相似文献
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Hao Dong Dawen Xu Wangsheng Liu Yaopeng Zhang Hao Guo 《Journal of Saudi Chemical Society》2019,23(8):1041-1048
An intramolecular-intermolecular cascade cyclization reaction via multi metal-carbene intermediates has been developed. This reaction uses catalytic amount of Nd(OTf)3, which actives both alkyne and aldehyde moieties. This protocol provides a novel strategy for the synthesis of phenanthro[9,10-b]furans. 相似文献
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Yirui Shen Pingping Jiang Phyu Thin Wai Pingbo Zhang Yuming Dong 《Journal of Saudi Chemical Society》2019,23(8):1157-1167
A facile post-synthetic strategy was developed to functionalize the preformed hollow mesoporous silica spheres by encapsulating the molybdenum dioxide (MoO2) nanoparticles inside the interior cavity. Hollow mesoporous silica spheres were prepared and employed as carriers, and the encapsulation of MoO2 nanoparticles was achieved through a one-pot hydrothermal protocol. After characterization, the encapsulated MoO2 nanoparticles were certified to be ultrafine and highly dispersed, which greatly promoted the catalytic activity. The as-prepared catalysts were utilized in epoxidation of alkenes and exhibited as a promising catalyst in this reaction. After reacting for 10 h, the optimal catalyst MoO2@SiO2-1 achieved a conversion above 95% and selectivity above 95%, respectively. Moreover, the catalysts also exhibited good reusability, conversion of 78% and selectivity of 89% (reaction time 4 h) were still obtained after recycling for 5 times. Meanwhile, the employed facial and efficient hydrothermal approach could be expanded to other molybdenum modified heterogeneous catalysts in various applications. 相似文献
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Meng Zang Chaocheng Zhao Yongqiang Wang Shuiquan Chen 《Journal of Saudi Chemical Society》2019,23(6):645-654
Along with the rapid development of industry, VOCs gradually move into the spotlight, and now become a kind of harmful environmental pollutants that cannot be overlooked. This paper introduces the hazards of VOCs and the common catalytic combustion catalysts, noble metal catalysts and non-noble metal catalysts, for the elimination of VOCs. Perovskite catalysts, as one of the non-noble catalysts, play an important role in the field of catalytic combustion in recent years. According to the classification of elements doping in perovskites, the research achievements in the past five years were analyzed and reviewed. In addition, this paper also analyzes and elaborates the reaction kinetics and QSAR/QSPR models for the introduction of structural properties and reaction mechanisms. 相似文献
120.
目的 了解鄞州区0~6月龄婴儿发育性髋关节异常(developmental dysplasia of hip,DDH)的流行病学特征,探讨DDH 的临床管理模式。方法 由鄞州区妇幼保健机构社区医师和鄞州区第二医院围生医生共同负责完成DDH 的临床初筛工作,可疑或异常者转儿科进一步检查,并予B 超筛查,对不同人群分别进行早期干预、复查、随访及骨盆正位X 线片检查,必要时转小儿骨科治疗。结果 2012 年5 月至2013 年5 月,共6 890 例0~6月龄婴儿进行髋关节B 超筛查,初筛阳性率5.73%(395/6 890),复查阳性率0.59%(34/5729);月龄越小筛查阳性率越高,差异有统计学意义(P<0.05)。新生儿及1~3月龄婴儿初筛阳性率高,但复查阳性率明显降低,差异有统计学意义(P<0.05);4~6月龄婴儿初筛及复查阳性率差异无统计学意义(P >0.05)。结论 鄞州区采取的社区门诊检查- 区医院儿科复查-B 超筛查及转诊治疗的管理模式,可作为基层推进DDH 的早发现和早治疗的有效手段。 相似文献